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The Effects of Cyclodextrins on the Reduction of Ninhydrin with N-Alky1-1, 4-dihydronicotinamides
https://kougei.repo.nii.ac.jp/records/124
https://kougei.repo.nii.ac.jp/records/1247cf6967b-4de5-43a0-a358-b3b16131b359
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KJ00002353295.pdf (423.9 kB)
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| Item type | [ELS]紀要論文 / Departmental Bulletin Paper(1) | |||||
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| 公開日 | 2017-04-21 | |||||
| タイトル | ||||||
| タイトル | The Effects of Cyclodextrins on the Reduction of Ninhydrin with N-Alky1-1, 4-dihydronicotinamides | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 雑誌書誌ID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00159741 | |||||
| 論文名よみ | ||||||
| タイトル | The Effects of Cyclodextrins on the Reduction of Ninhydrin with N-Alky1-1, 4-dihydronicotinamides | |||||
| 著者 |
高橋, 圭子
× 高橋, 圭子× UEMATSU, Masazumi× SONEDA, Yukihiro× 服部, 憲治郎× TAKAHASHI, Keiko× UEMATSU, Masazumi× SONEDA, Yukihiro× HATTORI, Kenjiro |
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| 著者所属(英) | ||||||
| en | ||||||
| The Faculty of Engineering Tokyo Institute of Polytechnics | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| The Faculty of Engineering Tokyo Institute of Polytechnics | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| The Faculty of Engineering Tokyo Institute of Polytechnics | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| Departmento Indsutrial chemistry | ||||||
| 記事種別(日) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 論文 | |||||
| 記事種別(英) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Article | |||||
| 抄録(英) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The effects of adding various cyclodextrins (α-,β- and γ-cyclodextrin) on the redox reaction between N-alky1-1, 4-dihydronicotinamide (hydride ion donnor) and ninhydrin (hydride ion acceptor) in aqueous solutions were studied kinetically. These reactions proceed through the hydride ion donnor-acceptor complex (CT complex) formation without cyclodextrin (CD). The presence of CD especially affects the reduction with N-benzy1-1,4-dihydronicotinamide (BNAH). β-CD is most effective for decreasing the reduction rate in three CDs. β-CD inhibited the formation of the CT complex by including BNAH molecule, which caused a decrease in the reaction rate. β-CD also completely inhibited the hydration of BNAH. γ-CD also included BNAH, however, it had little effect on the reduction rate constant. α-CD had no effect on both the reduction and the hydration. These inhibition behaviors were caused by an inclusion complex formation with CD. | |||||
| 書誌情報 |
東京工芸大学工学部紀要 en : The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 巻 9, 号 1, p. 46-52, 発行日 1986 |
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| 表示順 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 10 | |||||
| アクセション番号 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | KJ00002353295 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 03876055 | |||||
