{"created":"2023-06-20T13:23:12.780850+00:00","id":124,"links":{},"metadata":{"_buckets":{"deposit":"c63790ce-cc38-4709-a68a-059c3941e805"},"_deposit":{"created_by":3,"id":"124","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"124"},"status":"published"},"_oai":{"id":"oai:kougei.repo.nii.ac.jp:00000124","sets":["12:17:34:35"]},"author_link":["3249","286","178","289","288","180","287","3250"],"item_2_biblio_info_12":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1986","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"52","bibliographicPageStart":"46","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"東京工芸大学工学部紀要"},{"bibliographic_title":"The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University","bibliographic_titleLang":"en"}]}]},"item_2_description_11":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"The effects of adding various cyclodextrins (α-,β- and γ-cyclodextrin) on the redox reaction between N-alky1-1, 4-dihydronicotinamide (hydride ion donnor) and ninhydrin (hydride ion acceptor) in aqueous solutions were studied kinetically. These reactions proceed through the hydride ion donnor-acceptor complex (CT complex) formation without cyclodextrin (CD). The presence of CD especially affects the reduction with N-benzy1-1,4-dihydronicotinamide (BNAH). β-CD is most effective for decreasing the reduction rate in three CDs. β-CD inhibited the formation of the CT complex by including BNAH molecule, which caused a decrease in the reaction rate. β-CD also completely inhibited the hydration of BNAH. γ-CD also included BNAH, however, it had little effect on the reduction rate constant. α-CD had no effect on both the reduction and the hydration. These inhibition behaviors were caused by an inclusion complex formation with CD.","subitem_description_type":"Other"}]},"item_2_description_15":{"attribute_name":"表示順","attribute_value_mlt":[{"subitem_description":"10","subitem_description_type":"Other"}]},"item_2_description_16":{"attribute_name":"アクセション番号","attribute_value_mlt":[{"subitem_description":"KJ00002353295","subitem_description_type":"Other"}]},"item_2_description_8":{"attribute_name":"記事種別(日)","attribute_value_mlt":[{"subitem_description":"論文","subitem_description_type":"Other"}]},"item_2_description_9":{"attribute_name":"記事種別(英)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_source_id_1":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00159741","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03876055","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"The Faculty of Engineering Tokyo Institute of Polytechnics"},{"subitem_text_language":"en","subitem_text_value":"The Faculty of Engineering Tokyo Institute of Polytechnics"},{"subitem_text_language":"en","subitem_text_value":"The Faculty of Engineering Tokyo Institute of Polytechnics"},{"subitem_text_language":"en","subitem_text_value":"Departmento Indsutrial chemistry"}]},"item_2_title_3":{"attribute_name":"論文名よみ","attribute_value_mlt":[{"subitem_title":"The Effects of Cyclodextrins on the Reduction of Ninhydrin with N-Alky1-1, 4-dihydronicotinamides"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"高橋, 圭子"},{"creatorName":"タカハシ, ケイコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"178","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"UEMATSU, Masazumi"}],"nameIdentifiers":[{"nameIdentifier":"3249","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"SONEDA, Yukihiro"}],"nameIdentifiers":[{"nameIdentifier":"3250","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"服部, 憲治郎"},{"creatorName":"ハットリ, ケンジロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"180","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"TAKAHASHI, Keiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"286","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"UEMATSU, Masazumi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"287","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"SONEDA, Yukihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"288","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"HATTORI, Kenjiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"289","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-04-21"}],"displaytype":"detail","filename":"KJ00002353295.pdf","filesize":[{"value":"423.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00002353295.pdf","url":"https://kougei.repo.nii.ac.jp/record/124/files/KJ00002353295.pdf"},"version_id":"1155a6c2-50ac-4a2e-9d3e-ffa2b4a67b4f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"The Effects of Cyclodextrins on the Reduction of Ninhydrin with N-Alky1-1, 4-dihydronicotinamides","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The Effects of Cyclodextrins on the Reduction of Ninhydrin with N-Alky1-1, 4-dihydronicotinamides","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["35"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-04-21"},"publish_date":"2017-04-21","publish_status":"0","recid":"124","relation_version_is_last":true,"title":["The Effects of Cyclodextrins on the Reduction of Ninhydrin with N-Alky1-1, 4-dihydronicotinamides"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T13:45:42.653687+00:00"}