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Hydrolytic Catalysis with Complexation by Modified Cyclodextrins Having Diastereomeric Structure
https://kougei.repo.nii.ac.jp/records/45
https://kougei.repo.nii.ac.jp/records/45692f2482-8656-4f53-bff0-0eee086a6cbb
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KJ00001511864.pdf (734.6 kB)
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| Item type | [ELS]紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-04-21 | |||||
| タイトル | ||||||
| タイトル | Hydrolytic Catalysis with Complexation by Modified Cyclodextrins Having Diastereomeric Structure | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 雑誌書誌ID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00159741 | |||||
| 論文名よみ | ||||||
| タイトル | Hydrolytic Catalysis with Complexation by Modified Cyclodextrins Having Diastereomeric Structure | |||||
| 著者 |
ONOZUKA, Shigeharu
× ONOZUKA, Shigeharu× TODA, Fujio× 服部, 憲治郎× ONOZUKA, Shigeharu× TODA, Fujio× HATTORI, Kenjiro |
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| 著者所属(英) | ||||||
| en | ||||||
| Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| Department of Industrial Chemisty, Faculty of Engineering, Tokyo Institute of Polytechnics | ||||||
| 記事種別(日) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 論文 | |||||
| 記事種別(英) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Article | |||||
| 抄録(英) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | At the presence of three regiospecifically modified cyclodextrins, i. e., β-CD-D-histidine (I_D), β-CD-L-histidine (I_L) and β-CD-histamine (III), the ester cleavage at neutral pH was compared concerning in enantiomeric selectivity as well as rate enhancement. Micha-elis-Menten-type kinetics were observed for I_D and I_L in the phenol release of acetylanyl (and phenylalanyl) p-nitrophenyl ester enantiomers. Second order rate constants were obtained for III. Stereochemical comparisons of the spatial geometry in the complexes were discussed and also the schematic scheme of the host-guest fit was discussed. | |||||
| 書誌情報 |
東京工芸大学工学部紀要 en : The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 巻 3, 号 1, p. 32-42, 発行日 1980 |
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| 表示順 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 6 | |||||
| アクセション番号 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | KJ00001511864 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 03876055 | |||||
