{"created":"2023-06-20T13:23:07.881844+00:00","id":45,"links":{},"metadata":{"_buckets":{"deposit":"fd43fefe-4930-458b-a512-e8281f284629"},"_deposit":{"created_by":3,"id":"45","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"45"},"status":"published"},"_oai":{"id":"oai:kougei.repo.nii.ac.jp:00000045","sets":["12:17:24:25"]},"author_link":["70","3233","72","71","180","3234"],"item_2_biblio_info_12":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1980","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"42","bibliographicPageStart":"32","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"東京工芸大学工学部紀要"},{"bibliographic_title":"The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University","bibliographic_titleLang":"en"}]}]},"item_2_description_11":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"At the presence of three regiospecifically modified cyclodextrins, i. e., β-CD-D-histidine (I_D), β-CD-L-histidine (I_L) and β-CD-histamine (III), the ester cleavage at neutral pH was compared concerning in enantiomeric selectivity as well as rate enhancement. Micha-elis-Menten-type kinetics were observed for I_D and I_L in the phenol release of acetylanyl (and phenylalanyl) p-nitrophenyl ester enantiomers. Second order rate constants were obtained for III. Stereochemical comparisons of the spatial geometry in the complexes were discussed and also the schematic scheme of the host-guest fit was discussed.","subitem_description_type":"Other"}]},"item_2_description_15":{"attribute_name":"表示順","attribute_value_mlt":[{"subitem_description":"6","subitem_description_type":"Other"}]},"item_2_description_16":{"attribute_name":"アクセション番号","attribute_value_mlt":[{"subitem_description":"KJ00001511864","subitem_description_type":"Other"}]},"item_2_description_8":{"attribute_name":"記事種別(日)","attribute_value_mlt":[{"subitem_description":"論文","subitem_description_type":"Other"}]},"item_2_description_9":{"attribute_name":"記事種別(英)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_source_id_1":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00159741","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03876055","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo"},{"subitem_text_language":"en","subitem_text_value":"Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo"},{"subitem_text_language":"en","subitem_text_value":"Department of Industrial Chemisty, Faculty of Engineering, Tokyo Institute of Polytechnics"}]},"item_2_title_3":{"attribute_name":"論文名よみ","attribute_value_mlt":[{"subitem_title":"Hydrolytic Catalysis with Complexation by Modified Cyclodextrins Having Diastereomeric Structure"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ONOZUKA, Shigeharu"}],"nameIdentifiers":[{"nameIdentifier":"3233","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"TODA, Fujio"}],"nameIdentifiers":[{"nameIdentifier":"3234","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"服部, 憲治郎"},{"creatorName":"ハットリ, ケンジロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"180","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"ONOZUKA, Shigeharu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"70","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"TODA, Fujio","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"HATTORI, Kenjiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-04-21"}],"displaytype":"detail","filename":"KJ00001511864.pdf","filesize":[{"value":"734.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00001511864.pdf","url":"https://kougei.repo.nii.ac.jp/record/45/files/KJ00001511864.pdf"},"version_id":"d4c76127-b727-411a-8055-9f8752632276"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Hydrolytic Catalysis with Complexation by Modified Cyclodextrins Having Diastereomeric Structure","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Hydrolytic Catalysis with Complexation by Modified Cyclodextrins Having Diastereomeric Structure","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["25"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-04-21"},"publish_date":"2017-04-21","publish_status":"0","recid":"45","relation_version_is_last":true,"title":["Hydrolytic Catalysis with Complexation by Modified Cyclodextrins Having Diastereomeric Structure"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T13:46:10.286530+00:00"}