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Selective Cross-Acyloin Condensation Catalyzed by Thiazolium Salt II Selective Formation of 1-Hydroxy-2-ones form Formaldehyde and a Variety of Other Aldehydes, and a Proposal for the Possible Mechanism
https://kougei.repo.nii.ac.jp/records/142
https://kougei.repo.nii.ac.jp/records/14256902731-a6c9-40ee-a6b5-175e3a1f5dd2
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KJ00001511926.pdf (381.9 kB)
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| Item type | [ELS]紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-04-21 | |||||
| タイトル | ||||||
| タイトル | Selective Cross-Acyloin Condensation Catalyzed by Thiazolium Salt II Selective Formation of 1-Hydroxy-2-ones form Formaldehyde and a Variety of Other Aldehydes, and a Proposal for the Possible Mechanism | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 雑誌書誌ID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00159741 | |||||
| 論文名よみ | ||||||
| タイトル | Selective Cross-Acyloin Condensation Catalyzed by Thiazolium Salt II Selective Formation of 1-Hydroxy-2-ones form Formaldehyde and a Variety of Other Aldehydes, and a Proposal for the Possible Mechanism | |||||
| 著者 |
松本, 利彦
× 松本, 利彦× YOSHIDA, Atsuhiko× TAKAHASHI, Junko× 黒崎, 壽一× INOUE, Shohei× MATSUMOTO, Toshihiko× YOSHIDA, Atsuhiko× TAKAHASHI, Junko× KUROSAKI, Toshikazu× INOUE, Shohei |
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| 著者所属(英) | ||||||
| en | ||||||
| The Faculty of Engineering Tokyo Institute of Polytechnics | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| The Faculty of Engineering Tokyo Institute of Polytechnics | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| The Faculty of Engineering Tokyo Institute of Polytechnics | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| The Faculty of Engineering Tokyo Institute of Polytechnics, Department of Industrial Chemistry | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo | ||||||
| 記事種別(日) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 論文 | |||||
| 記事種別(英) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Article | |||||
| 抄録(英) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The selective cross-acyloin condensation, where 1-hydroxy-2-ones were obtained selectively from formaldehyde and a wide variety of other aldehydes, was achieved by using 3-ethylbenzothiazolium bromide as a catalyst in the presence of triethylamine. The present reaction is expected to afford a novel and facile method for the synthesis of 1-hydroxy-2-ones. A mechanism accounting for the selective formation of 1-hydroxy-2-one was proposed based on the results obtained by examining the reactions between formaldehyde and P-substituted benzaldehydes. It is of much interest in the mechanism that two catalytic species show an inverse selectivity toward aldehydes. | |||||
| 書誌情報 |
東京工芸大学工学部紀要 en : The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 巻 10, 号 1, p. 64-70, 発行日 1987 |
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| 表示順 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 11 | |||||
| アクセション番号 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | KJ00001511926 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 03876055 | |||||
