{"created":"2023-06-20T13:23:14.199772+00:00","id":142,"links":{},"metadata":{"_buckets":{"deposit":"6f811280-7d0b-4927-8a9d-3b11d4f4a1e5"},"_deposit":{"created_by":3,"id":"142","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"142"},"status":"published"},"_oai":{"id":"oai:kougei.repo.nii.ac.jp:00000142","sets":["12:17:36:37"]},"author_link":["3254","331","328","330","329","332","429","430","3255","3253"],"item_2_biblio_info_12":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1987","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"70","bibliographicPageStart":"64","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"東京工芸大学工学部紀要"},{"bibliographic_title":"The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University","bibliographic_titleLang":"en"}]}]},"item_2_description_11":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"The selective cross-acyloin condensation, where 1-hydroxy-2-ones were obtained selectively from formaldehyde and a wide variety of other aldehydes, was achieved by using 3-ethylbenzothiazolium bromide as a catalyst in the presence of triethylamine. The present reaction is expected to afford a novel and facile method for the synthesis of 1-hydroxy-2-ones. A mechanism accounting for the selective formation of 1-hydroxy-2-one was proposed based on the results obtained by examining the reactions between formaldehyde and P-substituted benzaldehydes. It is of much interest in the mechanism that two catalytic species show an inverse selectivity toward aldehydes.","subitem_description_type":"Other"}]},"item_2_description_15":{"attribute_name":"表示順","attribute_value_mlt":[{"subitem_description":"11","subitem_description_type":"Other"}]},"item_2_description_16":{"attribute_name":"アクセション番号","attribute_value_mlt":[{"subitem_description":"KJ00001511926","subitem_description_type":"Other"}]},"item_2_description_8":{"attribute_name":"記事種別(日)","attribute_value_mlt":[{"subitem_description":"論文","subitem_description_type":"Other"}]},"item_2_description_9":{"attribute_name":"記事種別(英)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_source_id_1":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00159741","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03876055","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"The Faculty of Engineering Tokyo Institute of Polytechnics"},{"subitem_text_language":"en","subitem_text_value":"The Faculty of Engineering Tokyo Institute of Polytechnics"},{"subitem_text_language":"en","subitem_text_value":"The Faculty of Engineering Tokyo Institute of Polytechnics"},{"subitem_text_language":"en","subitem_text_value":"The Faculty of Engineering Tokyo Institute of Polytechnics, Department of Industrial Chemistry"},{"subitem_text_language":"en","subitem_text_value":"Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo"}]},"item_2_title_3":{"attribute_name":"論文名よみ","attribute_value_mlt":[{"subitem_title":"Selective Cross-Acyloin Condensation Catalyzed by Thiazolium Salt II Selective Formation of 1-Hydroxy-2-ones form Formaldehyde and a Variety of Other Aldehydes, and a Proposal for the Possible Mechanism"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"松本, 利彦"},{"creatorName":"マツモト, トシヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"429","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"YOSHIDA, Atsuhiko"}],"nameIdentifiers":[{"nameIdentifier":"3253","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"TAKAHASHI, Junko"}],"nameIdentifiers":[{"nameIdentifier":"3254","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"黒崎, 壽一"},{"creatorName":"クロサキ, トシカズ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"430","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"INOUE, Shohei"}],"nameIdentifiers":[{"nameIdentifier":"3255","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"MATSUMOTO, Toshihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"328","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"YOSHIDA, Atsuhiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"329","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"TAKAHASHI, Junko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"330","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"KUROSAKI, Toshikazu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"331","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"INOUE, Shohei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"332","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-04-21"}],"displaytype":"detail","filename":"KJ00001511926.pdf","filesize":[{"value":"381.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00001511926.pdf","url":"https://kougei.repo.nii.ac.jp/record/142/files/KJ00001511926.pdf"},"version_id":"7863c40f-81bf-4f80-8ee1-951bc863c9ff"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Selective Cross-Acyloin Condensation Catalyzed by Thiazolium Salt II Selective Formation of 1-Hydroxy-2-ones form Formaldehyde and a Variety of Other Aldehydes, and a Proposal for the Possible Mechanism","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Selective Cross-Acyloin Condensation Catalyzed by Thiazolium Salt II Selective Formation of 1-Hydroxy-2-ones form Formaldehyde and a Variety of Other Aldehydes, and a Proposal for the Possible Mechanism","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["37"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-04-21"},"publish_date":"2017-04-21","publish_status":"0","recid":"142","relation_version_is_last":true,"title":["Selective Cross-Acyloin Condensation Catalyzed by Thiazolium Salt II Selective Formation of 1-Hydroxy-2-ones form Formaldehyde and a Variety of Other Aldehydes, and a Proposal for the Possible Mechanism"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T13:45:34.798456+00:00"}