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Acetohydroxamic Acid for Peptide Synthesis
https://kougei.repo.nii.ac.jp/records/20
https://kougei.repo.nii.ac.jp/records/207c2b6bca-f73e-4330-82b8-56e159fd0db6
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KJ00001511856.pdf (626.4 kB)
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| Item type | [ELS]紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-04-21 | |||||
| タイトル | ||||||
| タイトル | Acetohydroxamic Acid for Peptide Synthesis | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 雑誌書誌ID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00159741 | |||||
| 論文名よみ | ||||||
| タイトル | Acetohydroxamic Acid for Peptide Synthesis | |||||
| 著者 |
TERAMOTO, Takero
× TERAMOTO, Takero× KUROSAKI, Toshikazu× OKAWARA, Makoto× TERAMOTO, Takero× NARITA, Mitsuaki× KUROSAKI, Toshikazu× OKAWARA, Makoto |
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| 著者所属(英) | ||||||
| en | ||||||
| Lecturer, Professor, Department of Industrial Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| Assistant Professor, Department of Industrial Chemistry, Tokyo University of Agriculture and Technology | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| Lecturer, Professor, Department of Industrial Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics | ||||||
| 著者所属(英) | ||||||
| en | ||||||
| Research Laboratory of Resources Utilization, Tokyo Institute of Technology | ||||||
| 記事種別(日) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 論文 | |||||
| 記事種別(英) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Article | |||||
| 抄録(英) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The ester derivatives of acetohydroxamic acid md N, N-diacetyl hydroxylamine, N, O-diacetyl hydroxylamine and triacetyl hydroxylamine were assured to be capable of being used as activated esters. At first, evaluation of acyl activating ability was made by reacting the above compounds with amine, and it was shown that all of them worked to yield amides with excellent conversion and that, among them, triacetyy hydroxylamine was most powerfull, where acetylation of amines went through its imide carbonyl group. Furthemore, dipeptide synthesis was found to accomplish without any racemization and in a good yield by use of acetohydroxamic acid. Next syntheses of polymers containing hydroxamic acid structure were carried out by the following routes. (a) methyl methacrylate was copolymerized with N-methacrylobenzyloxyamine and the copolymer obtained was debenzylated, (b) N-methacrylo-N, O-diacetyl hydroxylamine was polymerized, followed by hydrolysis and copolymers with styrene or methyl methacrylate were deacylated. The polymer obtained by route (a) was converted to the activated polymer ester of N-blocked diglycine and removal of the protecting group would provide a method for preparation of cyclic diglycine. | |||||
| 書誌情報 |
東京工芸大学工学部紀要 en : The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 巻 2, 号 1, p. 43-52, 発行日 1979 |
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| 表示順 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 6 | |||||
| アクセション番号 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | KJ00001511856 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 03876055 | |||||
