@article{oai:kougei.repo.nii.ac.jp:00000086, author = {高橋, 圭子 and 野口, 真志 and 服部, 憲治郎 and TAKAHASHI, Keiko and NOGUCHI, Masashi and HATTORI, Kenjiro}, issue = {1}, journal = {東京工芸大学工学部紀要, The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University}, month = {}, note = {The fact that α-biotin serves as a covalently bound "C0_2 carrier" is now unequivocally established. Though model studies such as carboxylation on ureid l'-N-of biotin has been reported, no appropriate biomimetic model study for a "C0_2 carrier" has been carried out. The titled compound(I)in which the biotinyl group is bound to an amide linkage withβ-cyclodextrin, was prepared with active-ester method in good yield. Compound I was purified by taking with preparative HPLC. The structure of (I) was providedby ^1H-nmr, ^<13>C-nmr, elemental analysis, HPLC and the paper choromatography of hydrolyzates, and decided to be 6-(mono-N-biotinyl)-amino-β-cyclodextrin., 8, KJ00002409580, 論文, Article}, pages = {47--52}, title = {N-ビオチニル-アミノ-β-シクロデキストリン ノ ゴウセイ}, volume = {7}, year = {1984}, yomi = {タカハシ, ケイコ and ノグチ, マサシ and ハットリ, ケンジロウ} }