{"created":"2023-06-20T13:23:30.518738+00:00","id":376,"links":{},"metadata":{"_buckets":{"deposit":"5907c6a2-24be-4d75-99c9-5c9211121ce8"},"_deposit":{"created_by":3,"id":"376","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"376"},"status":"published"},"_oai":{"id":"oai:kougei.repo.nii.ac.jp:00000376","sets":["12:17:66:67"]},"author_link":["982","983","3121","981"],"item_2_biblio_info_12":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2001","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"38","bibliographicPageStart":"32","bibliographicVolumeNumber":"24","bibliographic_titles":[{"bibliographic_title":"東京工芸大学工学部紀要"},{"bibliographic_title":"The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University","bibliographic_titleLang":"en"}]}]},"item_2_description_11":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"Asymmetrically substituted linear polysilanes are important as new functional materials because of their good film forming ability in addition to the unique properties of polysilanes. In order to obtain these polymers, asymmetrically substituted monomers has been used. However, preparation of such monomers requires several reaction steps and that makes the total yield of the target polymers very low. In order to establish a better preparation pathway, here presented new method utilized monosubstituted trichloromonomers, (^1RSiCl_3). First, partial electrochemical reduction of the monomers was carried out to obtain linear polymers, (^1RClSi)_n, and then subsequent reaction with Grignard reagent was carried out to introduce the second substituent group and to obtain the asymmetrically substituted polymers, (^1R^2RSi)_n. Thus obtained polymers contained more or less partial network structures in the dominating linear structures because of undesirable networking reactions during the electrochemical reactions. However they showed mostly the typical properties of linear polymers.","subitem_description_type":"Other"}]},"item_2_description_15":{"attribute_name":"表示順","attribute_value_mlt":[{"subitem_description":"7","subitem_description_type":"Other"}]},"item_2_description_16":{"attribute_name":"アクセション番号","attribute_value_mlt":[{"subitem_description":"KJ00000124178","subitem_description_type":"Other"}]},"item_2_description_8":{"attribute_name":"記事種別(日)","attribute_value_mlt":[{"subitem_description":"論文","subitem_description_type":"Other"}]},"item_2_description_9":{"attribute_name":"記事種別(英)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_source_id_1":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00159741","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03876055","subitem_source_identifier_type":"ISSN"}]},"item_2_text_6":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_value":"東京工芸大学大学院工学研究科光工学専攻"},{"subitem_text_value":"東京工芸大学工学部光工学科"}]},"item_2_title_3":{"attribute_name":"論文名よみ","attribute_value_mlt":[{"subitem_title":"トリクロロシラン ノ ブブン デンカイ カンゲン ニ ヨル ヒタイショウ チカン チョクサポリシランゴウセイ ノ ココロミ"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"戸塚, 深"},{"creatorName":"トツカ, シン","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"981","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"岡野, 光俊"},{"creatorName":"オカノ, ミツトシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"3121","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Totsuka, Shin","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"982","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okano, Mitsutoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"983","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-04-21"}],"displaytype":"detail","filename":"KJ00000124178.pdf","filesize":[{"value":"538.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00000124178.pdf","url":"https://kougei.repo.nii.ac.jp/record/376/files/KJ00000124178.pdf"},"version_id":"ebfdcdd7-b8a9-458e-8703-c44abb6c6b3a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"トリクロロシランの部分電解還元による非対称置換直鎖ポリシラン合成の試み","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"トリクロロシランの部分電解還元による非対称置換直鎖ポリシラン合成の試み"},{"subitem_title":"A New reaction Pathway to Asymmetrically Substituted Linear Polysilanes via Partial Electrochemical Reduction of Trichlorosilanes","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["67"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-04-21"},"publish_date":"2017-04-21","publish_status":"0","recid":"376","relation_version_is_last":true,"title":["トリクロロシランの部分電解還元による非対称置換直鎖ポリシラン合成の試み"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T14:19:39.714792+00:00"}